Expeditious assembly of 3,4-benzannulated 8-oxabicyclo[3.2.1]octane systems by [2+2+2] alkyne cyclotrimerisation: Total synthesis of (-)-bruguierol A
Title | Expeditious assembly of 3,4-benzannulated 8-oxabicyclo[3.2.1]octane systems by [2+2+2] alkyne cyclotrimerisation: Total synthesis of (-)-bruguierol A |
Publication Type | Journal Article |
Year of Publication | 2007 |
Authors | Ramana, CV, Salian, SR, Gonnade, RG |
Journal | European Journal of Organic Chemistry |
Issue | 33 |
Pagination | 5483-5486 |
Date Published | NOV |
Type of Article | Article |
ISSN | 1434-193X |
Keywords | cyclotrimerisation, epoxidation, Total synthesis, Wilkinson's catalyst |
Abstract | Facile construction of benzene-fused 8-oxabicyclo[3.2.1]octane systems by employing a cross alkyne cyclotrimerisation reaction was explored. With this procedure, (-)-bruguierol A was synthesised, and its absolute configuration was established. |
DOI | 10.1002/ejoc.200700648 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 3.068 |
Divison category:
Organic Chemistry
Physical and Materials Chemistry