Ultrasound promoted asymmetric transfer hydrogenation of ketones using Ru(II)arene/amino alcohol catalyst system
| Title | Ultrasound promoted asymmetric transfer hydrogenation of ketones using Ru(II)arene/amino alcohol catalyst system |
| Publication Type | Journal Article |
| Year of Publication | 2008 |
| Authors | Shingote, SK, Kelkar, AA, Borole, YL, Joshi, PD, Chaudhari, RV |
| Journal | Ultrasonics Sonochemistry |
| Volume | 15 |
| Issue | 4 |
| Pagination | 289-293 |
| Date Published | APR |
| Type of Article | Article |
| ISSN | 1350-4177 |
| Keywords | asymmetric catalysis, transfer hydrogenation, Ultrasound |
| Abstract | Asymmetric transfer hydrogenation of ketones using Ru(II)arene/amino alcohol catalyst system proceeds with significant rate enhancement by ultrasound promotion. Comparison of the silent reactions carried out at 25 degrees C with reactions under sonochemical activation at 25 degrees C clearly showed enhancement in catalytic activity by 5-10 times without significantly affecting the enantioselectivity. (C) 2007 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.ultsonch.2007.10.003 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.556 |
Divison category:
Catalysis and Inorganic Chemistry