Near-complete phase transfer of single-wall carbon nanotubes by covalent functionalization
Title | Near-complete phase transfer of single-wall carbon nanotubes by covalent functionalization |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Kakade, BA, Patil, S, Sathe, B, Gokhale, S, Pillai, V |
Journal | Journal of Chemical Sciences |
Volume | 120 |
Issue | 6 |
Pagination | 599-606 |
Date Published | NOV |
ISSN | 0253-4134 |
Keywords | Carbon nanotubes, microscopy, Microwave, Nanostructures, solubility of SWNTs |
Abstract | We describe here an efficient phase transfer of single wall carbon nanotubes (SWNTs) from aqueous to non-aqueous media using a unique amide functionalization route, where water soluble SWNTs (2.6 mg/mL) are effectively transferred to solvents like chloroform, toluene and CS(2). A maximum of 30 wt% of oxygenated groups have been generated on the side walls by rapid microwave treatment, leading to a solubility of more than 2.6 mg/mL in water. Approximate surface amine coverage of 50% has been accomplished after oxalyl chloride treatment as inferred from thermogravimetry and X-ray photoelectron spectroscopy by controlling several key parameters associated with the extent of functionalization including purity of the sample, temperature and time. |
DOI | 10.1007/s12039-008-0091-3 |
Type of Journal (Indian or Foreign) | Indian |
Impact Factor (IF) | 1.075 |