Selective binding of benzoquinone with a Pt-II-cyclophane constructed on the skeleton of N,N `-bis(salicylidene)-p-phenylenediamine: synthesis and spectroscopic studies
| Title | Selective binding of benzoquinone with a Pt-II-cyclophane constructed on the skeleton of N,N `-bis(salicylidene)-p-phenylenediamine: synthesis and spectroscopic studies |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Kumari, N, Prajapati, R, Dixit, M, Mishra, L |
| Journal | Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry |
| Volume | 48 |
| Issue | 12 |
| Pagination | 1644-1651 |
| Date Published | DEC |
| ISSN | 0376-4710 |
| Keywords | Coordination chemistry, Cyclophanes, Metallocyclophanes, platinum, Schiff bases |
| Abstract | The Schiff base NN'-bis(salicylidene)-p-phenylenediamine has been complexed with Pt(en)Cl-2 and the resulting Pt-II-cyclophane, [Pt(en)L](2)center dot 4PF(6), reacted with phenol, resorcinol, hydroquinone or benzoquinone in DMSO solution. Their binding has been monitored by the variation in the corresponding UV-visible and emission spectral patterns. The binding properties are compared with the earlier reported Zn-II-cyclophane [Zn(bpy)L](2) (bpy = 2,2'-bipyridine). A few solid adducts of phenol and benzoquinone with the Pt-II-cyclophane complex and hydroquinone as well as that of resorcinol with the Zn-cyclophane have also been synthesized and characterized. |
| Type of Journal (Indian or Foreign) | Indian |
| Impact Factor (IF) | 0.920 |
Divison category:
Physical and Materials Chemistry