Regiospecific oxyhalogenation of aromatics over SBA-15-supported nanoparticle group IV-VI metal oxides
| Title | Regiospecific oxyhalogenation of aromatics over SBA-15-supported nanoparticle group IV-VI metal oxides |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Saikia, L, Rajesh, M, Srinivas, D, Ratnasamy, P |
| Journal | Catalysis Letters |
| Volume | 137 |
| Issue | 3-4 |
| Pagination | 190-201 |
| Date Published | JUL |
| ISSN | 1011-372X |
| Keywords | Haloperoxidase activity, Ordered mesoporous silica, Oxyhalogenation of aromatics, SBA-15, Supported metal oxides |
| Abstract | TiO(x), VO(x), MoO(x) and WO(x) supported on SBA-15 exhibit efficient catalytic activity for oxyhalogenation of aromatics with the H(2)O(2)-halide ion system. Unlike the hitherto known solid catalysts, these reusable catalysts yield the para-halogenated product with 100% selectivity at 298 K and moderate acidic pH (3-5). The catalytic activity was enhanced by five orders of magnitude when supported on SBA-15. |
| DOI | 10.1007/s10562-010-0350-z |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 1.907 |
Divison category:
Catalysis and Inorganic Chemistry