RuCl3-TBHP mediated allylic oxidation of Delta(8(9)) lanosterol derivatives

TitleRuCl3-TBHP mediated allylic oxidation of Delta(8(9)) lanosterol derivatives
Publication TypeJournal Article
Year of Publication2011
AuthorsShingate, BB, Hazra, BG, Salunke, DB, Pore, VS
JournalTetrahedron Letters
Volume52
Issue45
Pagination6007-6010
Date PublishedNOV
ISSN0040-4039
KeywordsAllylic oxidation, Oxygenated steroids, Ruthenium chloride, Steroidal ketones, t-Butyl hydroperoxide
Abstract

A variety of Delta(8(9))-lanosterol derivatives were converted into 7,11-dienones using t-butyl hydroperoxide in the presence of ruthenium chloride (RuCl3) in good yields. (C) 2011 Elsevier Ltd. All rights reserved.

DOI10.1016/j.tetlet.2011.08.166
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.683
Divison category: 
Organic Chemistry