Charge transport in functionalized multi-wall carbon nanotube-Nafion composite
Title | Charge transport in functionalized multi-wall carbon nanotube-Nafion composite |
Publication Type | Journal Article |
Year of Publication | 2012 |
Authors | Sangeeth, CSSuchand, Kannan, R, Pillai, VK, Menon, R |
Journal | Journal of Applied Physics |
Volume | 112 |
Issue | 5 |
Pagination | 053706 |
Date Published | SEP |
ISSN | 0021-8979 |
Abstract | The charge transport in sulfonated multi-wall carbon nanotube (sMWNT)-Nafion composite is reported. The scanning electron microscope images of the composite, at 1 and 10 wt % of sMWNT, show that the nanotubes are well dispersed in polymer matrix, with conductivity values of 0.005 and 3.2 S/cm, respectively; and the percolation threshold is nearly 0.42 wt. %. The exponent (similar to 0.25) of the temperature dependence of conductivity in both samples indicates Mott's variable range hopping (VRH) transport. The conductance in 1 wt. % sample increases by three orders of magnitude at high electric-fields, consistent with VRH model. The negative magnetoresistance in 10 wt. % sample is attributed to the forward interference scattering mechanism in VRH transport. The ac conductance in 1 wt. % sample is expressed by sigma(omega) proportional to omega(s), and the temperature dependence of s follows the correlated barrier hopping model. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4749264] |
DOI | 10.1063/1.4749264 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.21 |