Direct synthesis of amides from amines using mesoporous Mn-SBA-12 and Mn-SBA-16 catalysts
| Title | Direct synthesis of amides from amines using mesoporous Mn-SBA-12 and Mn-SBA-16 catalysts |
| Publication Type | Journal Article |
| Year of Publication | 2013 |
| Authors | Kumar, A, Nepak, D, Srinivas, D |
| Journal | Catalysis Communications |
| Volume | 37 |
| Pagination | 36-40 |
| Date Published | JUL |
| ISSN | 1566-7367 |
| Keywords | Aerial oxidation, Amide synthesis, Benzyl amine, Manganese incorporated SBA-12 and SBA-16, Mesoporous Mn-silica catalyst |
| Abstract | Manganese incorporated SBA-12 and SBA-16 catalyze the tandem reaction of aliphatic primary amine, aerial oxygen and ammonia solution at moderate conditions producing amide in yields as high as 50 mol%. The Mn-SBA-12 and Mn-SBA-16 catalysts with Si/Mn output molar ratio in the range 230 to 748 were prepared by the direct hydrothermal synthesis method and characterized. Weak acidity and Mn in +3 oxidation state are the key factors enable the synthesis of product amide in high yields. (C) 2013 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.catcom.2013.03.020 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.32 |
Divison category:
Catalysis and Inorganic Chemistry