Methane reforming with carbon dioxide over La-Ni-x-Ce1-x mixed oxide catalysts
Title | Methane reforming with carbon dioxide over La-Ni-x-Ce1-x mixed oxide catalysts |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | Sagar, TV, Sreelatha, N, Hanmant, G, Upendar, K, Lingaiah, N, Rao, KSeetha Ram, Satyanarayana, CVV, Reddy, IAK, Prasad, PSSai |
Journal | Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry |
Volume | 53 |
Issue | 4-5 |
Pagination | 478-483 |
Date Published | FEB |
ISSN | 0376-4710 |
Keywords | Carbon dioxide reforming, Catalysts, Cerium, Dry reforming, Hydrothermal synthesis, Lanthanum, Methane reforming, Mixed oxides, Nickel |
Abstract | La-Ni-x-Ce1-x mixed oxide (0 <= x <= 1) catalysts have been hydrothermally prepared, characterized by physico-chemical techniques and evaluated for CO2 reforming of methane. High conversions are achieved for both methane and carbon dioxide over the LaNi0.6Ce0.4O3 catalyst tested under the conditions of CO2/CH4/N-2 ratio of 80/80/80. (total flow rate = 240 mL/min), space velocity of 28,800 h(-1) and at a temperature of 800 degrees C. The H-2/CO ratio in the syngas is stable at 0.93 +/- 0.02. Exchanging Ni with Ce, rather than with La as reported in the literature, appears to be a better option for the improved performance of the catalysts. |
Type of Journal (Indian or Foreign) | Indian |
Impact Factor (IF) | 0.84 |
Divison category:
Catalysis and Inorganic Chemistry