General approach to N-heterocyclic carbenes with a fused tetracyclic core: ligands for suzuki-miyaura cross-coupling reaction
| Title | General approach to N-heterocyclic carbenes with a fused tetracyclic core: ligands for suzuki-miyaura cross-coupling reaction |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Sutar, RL, Kumar, V, Shingare, RD, Thorat, S, Gonnade, RG, D. Reddy, S |
| Journal | European Journal of Organic Chemistry |
| Issue | 21 |
| Pagination | 4482-4486 |
| Date Published | JUL |
| ISSN | 1434-193X |
| Keywords | C-C coupling, carbenes, Homogeneous catalysis, N ligands, synthetic methods |
| Abstract | The synthesis of an N-heterocyclic carbene (NHC) based on a tetracyclic scaffold by using simple, general, and scalable chemistry is disclosed. The developed route is suitable for introducing multiple substitutions on the tetracyclic scaffold. The utility of the present NHC as a ligand in the Suzuki-Miyaura cross-coupling reaction is demonstrated with a low catalyst loading. |
| DOI | 10.1002/ejoc.201402378 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.13 |
Divison category:
Center for Material Characterization (CMC)
Organic Chemistry