Reactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2O2: synthesis and x-ray structure of an N-Phenyl TAML

TitleReactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2O2: synthesis and x-ray structure of an N-Phenyl TAML
Publication TypeJournal Article
Year of Publication2015
AuthorsWarner, GR, Mills, MR, Enslin, C, Pattanayak, S, Panda, C, Panda, TKumar, Gupta, SSen, Ryabov, AD, Collins, TJ
JournalChemistry A-European Journal
Volume21
Issue16
Pagination6226-6233
Date PublishedAPR
Type of ArticleArticle
ISSN0947-6539
KeywordsHydrogen peroxide, iron, kinetics, Oxidation, reaction mechanisms
Abstract

{The catalytic activity of the N-tailed (biuret) TAML (tetraamido macrocyclic ligand) activators [Fe{4-XC6H3-1,2-(NCOCMe2NCO)(2)NR}Cl](2-) (3; N atoms in boldface are coordinated to the central iron atom; the same nomenclature is used in for compounds 1 and 2 below), [X

DOI10.1002/chem.201406061
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)5.771
Divison category: 
Chemical Engineering & Process Development