Use of isoperibolic reaction calorimeter for the study of reaction kinetics of acetic anhydride hydrolysis reaction: effect of acetic anhydride and water ratio

TitleUse of isoperibolic reaction calorimeter for the study of reaction kinetics of acetic anhydride hydrolysis reaction: effect of acetic anhydride and water ratio
Publication TypeJournal Article
Year of Publication2022
AuthorsKumar, R, Tiwari, AKumar
JournalChemical and Process Engineering-Inzynieria Chemiczna I Procesowa
Volume43
Issue2
Pagination255-264
Date PublishedDEC
Type of ArticleArticle; Proceedings Paper
ISSN0208-6425
Keywordsacetic anhydride, Hydrolysis, kinetics, reaction calorimeter, Water
Abstract

Reaction kinetics of acetic anhydride hydrolysis reaction is being studied at a fixed reaction temperature and ambient pressure using an isoperibolic reaction calorimeter. Temperature versus time data along with heat and mass balance is used to determine the kinetics parameters i.e. activation energy and Arrhenius coefficient. It has been studied with the varying volumetric ratio of acetic anhydride and water; and kinetics parameters were compared and plotted for each ratio. Such a study has not been done previously to determine the kinetics dependency on varying the acetic anhydride water ratio. As the acetic anhydride hydrolysis reaction is exothermic in nature, the present study will help to decide the safe and suitable operating conditions such as concentration and temperature for conducting this reaction at plant scale. The kinetic data presented can be used further for the mathematical modeling and simulation of such exothermic hydrolysis reactions.

DOI10.24425/cpe.2022.140829
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

0.679

Divison category: 
Chemical Engineering & Process Development
Database: 
Web of Science (WoS)

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