Upcycling solid wastes: using abundant egg shell wastes for the greener production of lactic acid under ambient conditions

TitleUpcycling solid wastes: using abundant egg shell wastes for the greener production of lactic acid under ambient conditions
Publication TypeJournal Article
Year of Publication2025
AuthorsSreekantan, S, Sudhakaran, AKalappurak, Marimuthu, B
JournalJournal of Environmental Chemical Engineering
Volume13
Issue2
Pagination115603
Date PublishedAPR
Type of ArticleArticle
ISSN2213-2929
KeywordsBiomass, Lactic acid, Sustainability, Waste egg shell, Waste-to- chemicals
Abstract

In this study, we explore a sustainable approach to repurposing eggshell waste as a catalyst for the conversion of biomass-derived sucrose, sugar syrup, xylan, and cellulose into lactic acid, a chemical in high demand. Currently, lactic acid is industrially produced using lactic acid bacteria (LAB), which require precise pH control and temperature maintenance, complicating their application. Our work demonstrates a one-pot synthesis of lactic acid using calcined eggshells in an aqueous medium via simple thermal treatment. Comprehensive characterization of the eggshell catalyst was carried out using techniques such as XRD, BET, FT-IR, FE-SEM, XPS, and TGA, revealing that calcination above 700 degrees C transformed the eggshell into CaO, drastically altering its morphology and enhancing its basicity. At 200 degrees C, using 70 wt% of catalyst for 1 h, we achieved a remarkable 92 C-mol% lactic acid yield with excellent carbon balance. The increased basicity played a key role in selectively driving lactic acid production. Our approach offers a green, sustainable solution with significant implications for future research in valorizing waste materials and advancing bio-based chemical production.

DOI10.1016/j.jece.2025.115603
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

7.4

Divison category: 
Catalysis and Inorganic Chemistry
Database: 
Web of Science (WoS)

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