Unusual temperature dependence of salt effects for ``on water'' wittig reaction: hydrophobicity at the interface

TitleUnusual temperature dependence of salt effects for ``on water'' wittig reaction: hydrophobicity at the interface
Publication TypeJournal Article
Year of Publication2008
AuthorsTiwari, S, Kumar, A
JournalChemical Communications
Issue37
Pagination4445-4447
Date PublishedMAY
Type of ArticleArticle
ISSN1359-7345
Abstract

An unusual variation with temperature of the salt effects in aqueous Wittig reaction is observed, suggesting that hydrophobic acceleration of reactions comprising ``on water'' reactants is fundamentally different from that for reactions with small non-polar solutes.

DOI10.1039/b809127g
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)6.567
Divison category: 
Physical and Materials Chemistry