Unified strategy for silver-, base-, and oxidant-free direct arylation of C-H bonds

TitleUnified strategy for silver-, base-, and oxidant-free direct arylation of C-H bonds
Publication TypeJournal Article
Year of Publication2017
AuthorsSahoo, MK, Midya, SP, Landge, VG, Balaraman, E
JournalGreen Chemistry
Volume19
Issue9
Pagination2111-2117
Date PublishedMAY
Type of ArticleArticle
ISSN1463-9262
Abstract

Here, we report a dual catalytic approach for room temperature direct arylation of C-H bonds with aryldiazonium salts as a simple aryl group donor, also working as an internal oxidant via C-N-2 bond cleavage. This unified strategy has been achieved by the synergistic combination of visible-light metal-free photoredox and palladium catalysis under silver-, base-and/or additive-free conditions. The broad substrate scope, functional group tolerance, excellent regioselectivity and redox-neutral conditions of this process make it attractive for the effective synthesis of a wide range of important N-heterocyclic commodities such as dibenzo [b,d]azepine, carbazole and phenanthridine.

DOI10.1039/c6gc03438a
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)8.586
Divison category: 
Catalysis and Inorganic Chemistry

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