Ultrafast switching time and third order nonlinear coefficients of microwave treated single walled carbon nanotube suspensions

TitleUltrafast switching time and third order nonlinear coefficients of microwave treated single walled carbon nanotube suspensions
Publication TypeJournal Article
Year of Publication2009
AuthorsKamaraju, N, Kumar, S, Karthikeyan, B, Kakade, BA, Pillai, VK, Sood, AK
JournalJournal of Nanoscience and Nanotechnology
Volume9
Issue9
Pagination5550-5554
Date PublishedSEP
ISSN1533-4880
KeywordsNonlinear Optical Coefficients, SWCNT, Ultra-Fast Switching
Abstract

Microwave treated water soluble and amide functionalized single walled carbon nanotubes have been investigated using femtosecond degenerate pump-probe and nonlinear transmission experiments. The time resolved differential transmission using 75 femtosecond pulse with the central wavelength of 790 nm shows a bi-exponential ultrafast photo-bleaching with time constants of 160 fs (130 fs) and 920 fs (300 fs) for water soluble (amide functionalized) nanotubes. Open and closed aperture z-scans show saturation absorption and positive (negative) nonlinear refraction for water soluble (amide functionalized) nanotubes. Two photon absorption coefficient, beta(0) similar to 250 cm/GW (650 cm/GW) and nonlinear index, gamma similar to 15 cm(2)/pW (-30 cm(2)/pW) are obtained from the theoretical fit in the saturation limit to the data for two types of nanotubes.

DOI10.1166/jnn.2009.1184
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.351
Divison category: 
Physical and Materials Chemistry