Transition-metal-free regioselective one-pot synthesis of aryl sulfones from sodium sulfinates via quinone imine ketal
| Title | Transition-metal-free regioselective one-pot synthesis of aryl sulfones from sodium sulfinates via quinone imine ketal |
| Publication Type | Journal Article |
| Year of Publication | 2019 |
| Authors | Halder, P, Humne, VT, Mhaske, SB |
| Journal | Journal of Organic Chemistry |
| Volume | 84 |
| Issue | 3 |
| Pagination | 1372–1378 |
| Date Published | JAN |
| Type of Article | Article |
| Abstract | A novel, efficient, and regioselective transition-metal-free one-pot synthesis of aryl sulfones via the reactive quinone imine ketal intermediate is demonstrated using easily accessible bench-stable sulfinate salts. A broad range of functionality on p-anisidine substrates as well as sulfinate salts was tolerated under mild reaction conditions to provide the corresponding aryl sulfones in good to excellent yields. |
| DOI | 10.1021/acs.joc.8b02835 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.805 |
Divison category:
Organic Chemistry