Towards sustainable continuous production of azo dyes: possibilities and techno-economic analysis

TitleTowards sustainable continuous production of azo dyes: possibilities and techno-economic analysis
Publication TypeJournal Article
Year of Publication2021
AuthorsShukla, CA, Kute, MS, Kulkarni, AA
JournalGreen Chemistry
Volume23
Issue17
Pagination6614-6624
Date PublishedSEP
Type of ArticleArticle
ISSN1463-9262
AbstractA novel continuous process for synthesizing azo dyes using a bubble column reactor is reported. Continuous experiments were successfully performed for Sudan-I dye and Solvent Yellow 16 dye with a yield [and productivity] of 92.04 +/- 3.50% [1.68 +/- 0.13 kg day(-1)] and 96.60 +/- 2.18% [1.92 +/- 0.04 kg day(-1)], respectively. Experiments were performed at a higher slurry concentration similar to 5% (w/w) without any clogging. The results were extended for performing a detailed techno-economic analysis for 5 TPD Sudan-I azo dye production as a case study. The results indicate that the cost of the continuous process is almost 4.68 times lower than that of the corresponding batch process. Furthermore, the footprint for a continuous plant can be lowered by 2.4 to 4.5 times when compared to the batch process depending on different refilling strategies for feed storage tanks. A continuous process may require 39-42% less water than the industrial batch process.
DOI10.1039/d1gc01133b
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)10.182
Divison category: 
Chemical Engineering & Process Development

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