Total synthesis of the putative structure of xylarinol B
Title | Total synthesis of the putative structure of xylarinol B |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | More, AA, Ramana, CV |
Journal | Chemistry-An Asian Journal |
Volume | 9 |
Issue | 6 |
Pagination | 1557-1562 |
Date Published | JUN |
ISSN | 1861-4728 |
Keywords | Chiral pool, cobalt, Natural products, structure elucidation, Total synthesis |
Abstract | The total synthesis of the putative structure of xylarinolB is described and the need to revise its structure is demonstrated. The central benzoxepine skeleton was constructed by employing a cobalt-mediated bimolecular [2+2+2] Reppe-Vollhardt alkyne cycloaddition reaction. |
DOI | 10.1002/asia.201301647 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 4.92 |
Divison category:
Organic Chemistry