Total synthesis of propolisbenzofuran B
Title | Total synthesis of propolisbenzofuran B |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Srinivas, K, Ramana, CV |
Journal | Organic Letters |
Volume | 19 |
Issue | 24 |
Pagination | 6466-6469 |
Date Published | DEC |
Type of Article | Article |
Abstract | An efficient synthesis of propolisbenzofuran B, which possesses promising anticancer activity, is reported. The key cyclohexanone framework of this tricyclic natural product has been constructed employing a Rh-catalyzed intramolecular olefin hydroacylation. The requisite key olefin intermediate was synthesized by using gold-catalyzed allenyl ether [1,3] O -> C rearrangement. |
DOI | 10.1021/acs.orglett.7b02732 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.579 |
Divison category:
Organic Chemistry
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