Total synthesis of pachastrissamine (jaspine B) enantiomers from D-glucose
| Title | Total synthesis of pachastrissamine (jaspine B) enantiomers from D-glucose |
| Publication Type | Journal Article |
| Year of Publication | 2007 |
| Authors | Ramana, CV, Giri, AG, Suryawanshi, SB, Gonnade, RG |
| Journal | Tetrahedron Letters |
| Volume | 48 |
| Issue | 2 |
| Pagination | 265-268 |
| Date Published | JAN |
| Type of Article | Article |
| ISSN | 0040-4039 |
| Keywords | 4-furanose, chiron approach, Ohira-Bestmann reaction, pachastrissamine/jaspine B, pentodialdo-1, ring isomerization |
| Abstract | Synthesis of both enantiomers of pachastrissamine is described from a common chiral template. The stereoselective construction of the central tetrahydrofuran units was based on the pseudodesymmetrization of a pentodialdo-1,4-furanose derivative taking advantage of the latent symmetry present. (c) 2006 Published by Elsevier Ltd. |
| DOI | 10.1016/j.tetlet.2006.11.048 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.347 |
Divison category:
Organic Chemistry
Physical and Materials Chemistry