Total synthesis of naturally occurring cephalosporolides E/F
Title | Total synthesis of naturally occurring cephalosporolides E/F |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | Kona, CNaidu, Ramana, CV |
Journal | Tetrahedron |
Volume | 70 |
Issue | 23 |
Pagination | 3653-3656 |
Date Published | JUN |
ISSN | 0040-4020 |
Keywords | Alkynetetrol, Cephalosporolide, Epoxide-alkyne coupling, Gold catalysis, Spiroketalization |
Abstract | A modular total synthesis of cephalosporolides E/F featuring sequential epoxide-alkyne coupling and subsequent highly regioselective gold catalyzed alkynolcycloisomerizatio of the resulting alkynetetrol to construct the central spiroketal core has been documented. (C) 2014 Elsevier Ltd. All rights reserved. |
DOI | 10.1016/j.tet.2014.04.026 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 2.68 |
Divison category:
Organic Chemistry