Total synthesis of mangiferaelactone
| Title | Total synthesis of mangiferaelactone |
| Publication Type | Journal Article |
| Year of Publication | 2014 |
| Authors | Vadhadiya, PM, Ramana, CV |
| Journal | Tetrahedron Letters |
| Volume | 55 |
| Issue | 45 |
| Pagination | 6263-6265 |
| Date Published | NOV |
| ISSN | 0040-4039 |
| Keywords | Bernet-Vasella fragmentation, Nonenolide, Ring closing metathesis, Total synthesis, Yamaguchi protocol |
| Abstract | Herein we document the first total synthesis of mangiferaelactone and thus establish its absolute configuration. The central nonenolide ring was constructed using ring closing metathesis and Yamaguchi esterification. The key alcohol fragment was synthesized by the Bernet-Vasella fragmentation of C-ribofuranoside. (C) 2014 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.tetlet.2014.09.084 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.68 |
Divison category:
Organic Chemistry