Titanium superoxide: a heterogeneous catalyst for anti-Markovnikov aminobromination of olefins
| Title | Titanium superoxide: a heterogeneous catalyst for anti-Markovnikov aminobromination of olefins |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Shaikh, TMahamadali, Karabal, PU, Suryavanshi, G, Sudalai, A |
| Journal | Tetrahedron Letters |
| Volume | 50 |
| Issue | 23 |
| Pagination | 2815-2817 |
| Date Published | JUN |
| ISSN | 0040-4039 |
| Keywords | anti-Markovnikov addition, Bromoamination, N-Bromosuccinimide, p-Toluenesulfonamide, Titanium superoxide |
| Abstract | A new facile procedure for the aminobromination of olefins in high yields has been described using p-toluene sulfonamide (p-TsNH(2)) and N-bromosuccinimide (NBS) as introgen and bromine sources, respectively, and titanium superoxide as a truly heterogeneous catalyst. The formation of anti-Markovnikov product exclusively in all the cases studied possibly proceeding I free radical reaction pathway is remarkable. (C) 2009 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.tetlet.2009.03.169 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.618 |
Divison category:
Chemical Engineering & Process Development