TiO2-Au plasmonic nanocomposite for enhanced dye-sensitized solar cell (DSSC) performance

TitleTiO2-Au plasmonic nanocomposite for enhanced dye-sensitized solar cell (DSSC) performance
Publication TypeJournal Article
Year of Publication2012
AuthorsMuduli, S, Game, OS, Dhas, VV, Vijayamohanan, K, Bogle, KA, Valanoor, N, Ogale, SB
JournalSolar Energy
Volume86
Issue5
Pagination1428-1434
Date PublishedMAY
ISSN0038-092X
KeywordsAnatase TiO2, Au, Dye-sensitized solar cells, Hybrid composite, hydrothermal
Abstract

Anatase TiO2 nanoparticles dressed with gold nanoparticles were synthesized by hydrothermal process by using mixed precursor and controlled conditions. Diffused Reflectance Spectra (DRS) reveal that in addition to the expected TiO2 interband absorption below 360 nm gold surface plasmon feature occurs near 564 nm. It is shown that the dye sensitized solar cells made using TiO2-Au plasmonic nanocomposite yield superior performance with conversion efficiency (CE) of similar to 6% (no light harvesting), current density (J(SC)) of similar to 13.2 mA/cm(2), open circuit voltage (V-oc) of similar to 0.74 V and fill factor (FF) 0.61; considerably better than that with only TiO2 nanoparticles (CE similar to 5%, J(SC) similar to 12.6 mA/cm(2), V-oc similar to 0.70 V, FF similar to 0.56). (C) 2012 Elsevier Ltd. All rights reserved.

DOI10.1016/j.solener.2012.02.002
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.952
Divison category: 
Physical and Materials Chemistry