Ti-superoxide catalyzed oxidative amidation of aldehydes with saccharin as nitrogen source: synthesis of primary amides
| Title | Ti-superoxide catalyzed oxidative amidation of aldehydes with saccharin as nitrogen source: synthesis of primary amides |
| Publication Type | Journal Article |
| Year of Publication | 2020 |
| Authors | Kamble, RB, Mane, KD, Rupanawar, BD, Korekar, P, Sudalai, A, Suryavanshi, G |
| Journal | RSC Advances |
| Volume | 10 |
| Issue | 2 |
| Pagination | 724-728 |
| Date Published | JAN |
| Type of Article | Article |
| Abstract | A new heterogeneous catalytic system (Ti-superoxide/saccharin/TBHP) has been developed that efficiently catalyzes oxidative amidation of aldehydes to produce various primary amides. The protocol employs saccharin as amine source and was found to tolerate a wide range of substrates with different functional groups. Moderate to excellent yields, catalyst reusability and operational simplicity are the main highlights. A possible mechanism and the role of the catalyst in oxidative amidation have also been discussed. |
| DOI | 10.1039/c9ra10413e |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.119 |
Divison category:
Chemical Engineering & Process Development