Thermal expansion properties of stannosilicate molecular sieve with MFI type structure
| Title | Thermal expansion properties of stannosilicate molecular sieve with MFI type structure |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | Niphadkar, PS, Bhange, DS, Selvaraj, K, Joshi, PN |
| Journal | Chemical Physics Letters |
| Volume | 548 |
| Pagination | 51-54 |
| Date Published | OCT |
| ISSN | 0009-2614 |
| Abstract | An in situ high temperature X-ray diffraction study was carried out for investigating the thermal expansion properties of Si-MFI and SnSi-MFI molecular sieves. The thermal stability up to 973 K and a negative lattice thermal expansion in anisotropic manner was exhibited by both the phases in the temperature range of 373-973 K. The trend observed in contraction along the axes was as: a > c > b. The substitution of Sn4+ in MFI framework resulted in an expansion of unit cell volume and in an increase in the lattice thermal expansion coefficient in the temperature range 423-973 K. (C) 2012 Elsevier B. V. All rights reserved. |
| DOI | 10.1016/j.cplett.2012.08.023 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.145 |
Divison category:
Catalysis and Inorganic Chemistry