Thallium(III) p-tosylate (TTS) mediated oxidative rearrangement of 2-naphthyl and 2-heteroarylchromanones
| Title | Thallium(III) p-tosylate (TTS) mediated oxidative rearrangement of 2-naphthyl and 2-heteroarylchromanones |
| Publication Type | Journal Article |
| Year of Publication | 2022 |
| Authors | Kurapati, C, Muthukrishnan, M, V. Singh, O, Gundla, R |
| Journal | Indian Journal of Chemistry |
| Volume | 61 |
| Issue | 9 |
| Pagination | 923-927 |
| Date Published | SEP |
| Type of Article | Article |
| ISSN | 0019-5103 |
| Keywords | 2-(3-pyridyl)chromones, 2-(4-pyridyl)chromones, 2-and 3-(2-theinyl)chromones, 2-and 3-(3-theinyl)chromones, 2-and 3-(?-naphthyl) chromones, Dehydrogenation, Oxidative rearrangements, thallium(III) acetate, thallium(III) p-tosylate |
| Abstract | A practical and effective approach towards the synthesis of 3-hetroaryl-4H-chromen-4-ones by the oxidative rearrangement of the respective 2-hetroaryl chroman-4-ones using thallium(III) p-tosylate is described. The oxidative rearrangement of alpha and beta-naphthyl and thiophene behave like aryl groups. However, pyridyl groups give only the dehydrogenated product. |
| DOI | 10.56042/ijc.v61i9.66341 |
| Type of Journal (Indian or Foreign) | Indian |
| Impact Factor (IF) | 0.491 |
Divison category:
Organic Chemistry
Database:
Web of Science (WoS)
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