Template induced structural isomerism and enhancement of porosity in manganese(II) based metal-organic frameworks (Mn-MOFs)
| Title | Template induced structural isomerism and enhancement of porosity in manganese(II) based metal-organic frameworks (Mn-MOFs) |
| Publication Type | Journal Article |
| Year of Publication | 2011 |
| Authors | Panda, T, Pachfule, P, Banerjee, R |
| Journal | Chemical Communications |
| Volume | 47 |
| Issue | 27 |
| Pagination | 7674-7676 |
| Date Published | JUN |
| ISSN | 1359-7345 |
| Abstract | Three new metal-organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO3)(2)center dot xH(2)O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sectional pore apertures of the resulting Mn-MOFs are comparable to the molecular dimensions of the template (pyrazine and 4,40-bipyridine). The periodic increased porosity in Mn-MOFs depending on the size of the template used has been further confirmed by the CO2 adsorption isotherms. |
| DOI | 10.1039/c1cc12278a |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 6.169 |
Divison category:
Physical and Materials Chemistry