Synthesis of La0.7Sr0.3MnO3 at 800 degrees C using citrate gel method

TitleSynthesis of La0.7Sr0.3MnO3 at 800 degrees C using citrate gel method
Publication TypeJournal Article
Year of Publication2007
AuthorsRavi, V, Kulkarni, SD, Samuel, V, Kale, SN, Mona, J, Rajgopal, R, Daundkar, A, Lahoti, PS, Joshi, RS
JournalCeramics International
Volume33
Issue6
Pagination1129-1132
Date PublishedAUG
Type of ArticleArticle
ISSN0272-8842
KeywordsCeramics, Citrate gel method, CMR, Oxides
Abstract

Manganite systems have been of considerable interest in the recent past due to their potential to operate in wide property range and also to serve as effective magnetic sensing and storing devices when synthesized using stringent conditions. We report a novel citrate gel method, in which La0.7Sr0.3MnO3 system has been synthesized at temperature 800 degrees C (LSMO800) with the synthesis duration is 6 h. The results have been compared with the sample synthesized at 1050 degrees C (LSMO1050). The synthesized bulk polycrystalline sample shows single-phase nature with the increase in particle size from similar to 50 nm to 300 nm with the increase in the sintering temperature. The magnetization data for LSMO800 shows well-defined hysteresis with saturation magnetization at around 1800 Oe and Curie temperature at 360 K, which is slightly lower than that of LSMO1050, which is 375 K. The results can be well attributed to the grain boundary effects. (C) 2006 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

DOI10.1016/j.ceramint.2006.02.008
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)2.758
Divison category: 
Center for Material Characterization (CMC)
Physical and Materials Chemistry