Synthesis of gamma-WO3 thin films by hot wire-CVD and investigation of its humidity sensing properties

TitleSynthesis of gamma-WO3 thin films by hot wire-CVD and investigation of its humidity sensing properties
Publication TypeJournal Article
Year of Publication2017
AuthorsJadkar, V, Pawbake, A, Waykar, R, Jadhavar, A, Date, A, Late, D, Pathan, H, Gosavi, S, Jadkar, S
JournalPhysica Status Solidi A-Applications and Materials Science
Volume214
Issue5
PaginationArticle Number: 1600717
Date PublishedMAY
Type of ArticleArticle
AbstractIn this study, monoclinic tungsten oxide (gamma-WO3) have been grown in a single step using HW-CVD method by resistively heating W filaments in a constant O-2 pressure. The formation of gamma-WO3 was confirmed using low angle-XRD and Raman spectroscopy analysis. Low angle-XRD analysis revealed that as-deposited WO3 film are highly crystalline and the crystallites have preferred orientation along the (002) direction. HRTEM analysis and SAED pattern also show the highly crystalline nature of WO3 with d spacing of similar to 0.38 nm, having an orientation along the (002) direction. Surface topography investigated by SEM analysis shows the formation of a uniform and homogeneous cauliflower like morphology throughout the substrate surface without flaws and cracks. A humidity sensing device incorporating WO3 is also fabricated, which shows a maximum humidity sensitivity factor of similar to 3954% along with a response time of similar to 14 s and a recovery time of similar to 25 s. The obtained results demonstrate that it is possible to synthesize WO3 in a single step by HW-CVD method and to fabricate a humidity sensor by using it. (C) 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
DOI10.1002/pssa.201600717
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)1.648
Divison category: 
Physical and Materials Chemistry

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