Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-amino-benzoxazole

TitleSynthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-amino-benzoxazole
Publication TypeJournal Article
Year of Publication2025
AuthorsRazzoqova, S, Ruzimov, Y, Toshov, A, Torambetov, B, Ibragimov, A, Ashurov, J, Kadirova, S
JournalActa Crystallographica Section E, Crystallographic Communications
Volume81
Pagination482-485
Date PublishedJUN
Type of ArticleArticle
Abstract

A coordination complex of cadmium nitrate [Cd(NO3)2] with 2-amino-benzaxole (2AB; C7H6N2O), namely, tetra-kis-(2-amino-benzoxazole-κN 1)bis-(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2·H2O and 2AB. The asymmetric unit comprises half a mol-ecule of [Cd(NO3)2(2AB)4], with the CdII atom positioned on a twofold rotation axis. In the completed mol-ecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the CdII atom, leading to a distorted octa-hedral coordination environment. The crystal structure of [Cd(NO3)2(2AB)4] exhibits several N-H⋯O inter-actions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to qu-antify the inter-molecular inter-actions.

DOI10.1107/S2056989025004049
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

0.6

Divison category: 
Physical and Materials Chemistry
Database: 
Web of Science (WoS)

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