Synthesis of chromium substituted nano particles of cobalt zinc ferrites by coprecipitation

TitleSynthesis of chromium substituted nano particles of cobalt zinc ferrites by coprecipitation
Publication TypeJournal Article
Year of Publication2005
AuthorsSharma, RK, Suwalka, O, Lakshmi, N, Venugopalan, K, Banerjee, A, Joy, PAlias
JournalMaterials Letters
Volume59
Issue27
Pagination3402-3405
Date PublishedNOV
Type of ArticleArticle
ISSN0167-577X
KeywordsCo0.5Zn0.5Fe2O4, Mossbauer spectroscopy, nano materials
Abstract

Nano particles of chromium substituted cobalt zinc ferrite have been synthesized by a chemical co-precipitation method. X-ray diffraction studies of the nano particles of CrxCo0.5-xZn0.5Fe2O4 (x = 0.1 to 0.5) heat-treated at 300 degrees C show that the particle sizes are in the range of 2 to 7 nm. Room temperature Fe-57 Mossbauer spectra of all the samples show only two doublets, confirming the presence of superparamagnetic relaxation in the nano particles. An exponential decrease in the superparamagnetic blocking temperature, with increasing chromium concentration, is observed for these samples. (C) 2005 Elsevier B.V. All rights reserved.

DOI10.1016/j.matlet.2005.06.004
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.437
Divison category: 
Physical and Materials Chemistry