Synthesis, characterization of chemically deposited indium selenide thin films at room temperature

TitleSynthesis, characterization of chemically deposited indium selenide thin films at room temperature
Publication TypeJournal Article
Year of Publication2008
AuthorsAsabe, MR, Chate, PA, Delekar, SD, Garadkar, KM, Mulla, IS, Hankare, PP
JournalJournal of Physics and Chemistry of Solids
Volume69
Issue1
Pagination249-254
Date PublishedJAN
Type of ArticleArticle
ISSN0022-3697
KeywordsChemical synthesis, Semiconductor
Abstract

Polycrystalline In2Se3 semiconducting thin films were prepared by using relatively simple chemical bath deposition method at room temperature by the reaction between indium chloride, tartaric acid, hydrazine hydrate and sodium selenosulphate in an aqueous alkaline medium. Various preparative conditions of thin film deposition are outlined. The as grown films were found to be transparent, uniform, well adherent and red in color. The films were characterized using X-ray diffraction (XRD), scanning electron microscopy, atomic absorption spectroscopy and energy dispersive atomic X-ray diffraction (EDAX). The XRD analysis of the film showed the presence of polycrystalline nature with hexagonal crystal structure. SEM study revels that the grains are homogenous, without cracks or pinholes and well covers the glass substrate. The optical absorption and electrical conductivity was measured. The direct optical band gap value for the films was found to be of the order of 2.35eV at room temperature and have specific electrical conductivity of the order of 10(-2) (Omega cm)(-1) showing n-type conduction mechanism. The utility of the adapted technique is discussed from the view-point of applications considering the optoelectric and structural data. (c) 2007 Elsevier Ltd. All rights reserved.

DOI10.1016/j.jpcs.2007.08.070
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)2.048
Divison category: 
Physical and Materials Chemistry