Synthesis, characterization, and crystal structure of 2-(2-azido­phen­yl)-3-oxo-3H-indole 1-oxide

TitleSynthesis, characterization, and crystal structure of 2-(2-azido­phen­yl)-3-oxo-3H-indole 1-oxide
Publication TypeJournal Article
Year of Publication2024
AuthorsDhote, P, Tothadi, S, Ramana, CV, Chopra, D
JournalActa Crystallographica Section E Crystallographic Communications
Volume80
Issue3
Pagination310-313
Date PublishedMAR
Abstract
An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen.
An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, C14H8N4O2. In the crystal structure, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions link the mol­ecules. The structure exhibits disorder of the mol­ecule.

 
DOI10.1107/S2056989024001440
Type of Journal (Indian or Foreign)

Foreign
Impact Factor (IF)

0.5
Divison category: 
Organic Chemistry
Database: 
Web of Science (WoS)