Synthesis, characterization and catalytic properties of hexagonal mesoporous vanadium aluminophosphate molecular sieves
| Title | Synthesis, characterization and catalytic properties of hexagonal mesoporous vanadium aluminophosphate molecular sieves |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Venkatathri, N, Srivastava, R |
| Journal | Catalysis Communications |
| Volume | 6 |
| Issue | 3 |
| Pagination | 177-183 |
| Date Published | MAR |
| Type of Article | Article |
| ISSN | 1566-7367 |
| Abstract | Novel vanadium containing hexagonal mesoporous aluminophosphate molecular sieve (VHMA) have been synthesized. XRD and TEM analysis confirm the phase purity of the synthesized samples. FT-IR analysis suggests the incorporation of V4+ in the aluminophosphate framework. ESR, UV-Vis spectroscopic techniques and cyclic voltammetric studies confirm the incorporation of vanadium and reveal its presence of tetrahedral and square pyramidal environments in the as-synthesized samples. Cyclic voltammetry reveals the presence of two redox couples in VHMA. This catalyst is found to be a good oxidation catalyst. (C) 2005 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.catcom.2004.12.005 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.389 |
Divison category:
Catalysis and Inorganic Chemistry