Synthesis, characterization and catalytic performance of Sn-MCM-48 in solvent-free Mukaiyama-type aldol condensation reactions
| Title | Synthesis, characterization and catalytic performance of Sn-MCM-48 in solvent-free Mukaiyama-type aldol condensation reactions |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Taralkar, US, Kalita, P, Kumar, R, Joshi, PN |
| Journal | Applied Catalysis A-General |
| Volume | 358 |
| Issue | 1 |
| Pagination | 88-94 |
| Date Published | APR |
| ISSN | 0926-860X |
| Keywords | Characterization, heterogeneous catalysis, Hydrothermal synthesis, Mesoporous molecular sieves, Mukaiyama-aldol condensation, Sn-MCM-48 |
| Abstract | The influence of various synthesis variables on the physico-chemical properties of mesoporous stannosilicate molecular sieves with MCM-48 structure (Sn-MCM-48) has been investigated. Sn-MCM48 has been used as a new heterogeneous catalyst in solvent-free Mukaiyama-type aldol reactions. Invariably, the beta-hydroxy ester selectivity was found to be 100% irrespective of the conversion level. The product yield was found to increase, to reach a maximum (70%), and then to decrease with the increase in tin content. (C) 2009 Elsevier B.V. All rights reserved. |
| DOI | 10.1016/j.apcata.2009.02.001 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.383 |
Divison category:
Catalysis and Inorganic Chemistry