Synthesis of C-2 methylene glycosides from C-2 propargyloxymethyl glycals exploiting the alkynophilicity of AuCl3
| Title | Synthesis of C-2 methylene glycosides from C-2 propargyloxymethyl glycals exploiting the alkynophilicity of AuCl3 |
| Publication Type | Journal Article |
| Year of Publication | 2007 |
| Authors | Kashyap, S, Vidadala, SRao, Hotha, S |
| Journal | Tetrahedron Letters |
| Volume | 48 |
| Issue | 51 |
| Pagination | 8960-8962 |
| Date Published | DEC |
| Type of Article | Article |
| ISSN | 0040-4039 |
| Abstract | C-2 Methylene glycosides were synthesized from C-2 propargyloxymethyl glycals in a stereoselective manner using a catalytic quantity of AuCl3. The Au-catalyzed reaction was explored using various aglycones. The current protocol enables the preparation of C-2 methylene glycosides, tolerates diverse functional groups and is fast, catalytic and mild. (c) 2007 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.tetlet.2007.10.144 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 2.347 |
Divison category:
Biochemical Sciences