Synthesis and characterization of partially bio-based polyimides based on biphenylene-containing diisocyanate derived from vanillic acid
| Title | Synthesis and characterization of partially bio-based polyimides based on biphenylene-containing diisocyanate derived from vanillic acid |
| Publication Type | Journal Article |
| Year of Publication | 2018 |
| Authors | Kuhire, SS, Ichake, AB, Grau, E, Cramail, H, Wadgaonkar, PP |
| Journal | European Polymer JOurnal |
| Volume | 109 |
| Pagination | 257-264 |
| Date Published | DEC |
| Type of Article | Article |
| ISSN | 0014-3057 |
| Abstract | A new bio-based biphenylene-containing diisocyanate, namely, 5,5'-diisocyanato-2,2',3,3'-tetramethoxy-1,1'-biphenyl (BDI) was synthesized starting from vanillic acid - a lignin-derived phenolic acid. A series of new partially bio-based polyimides was prepared by polycondensation of BDI with five commercially available aromatic dianhydrides. Polyimides exhibited good solubility in organic solvents and medium molecular weights (Mn (GPC, polystyrene standard) = 25,100-32,200 g mol(-1)). Polyimides showed good thermal stability with 10% degradation temperature and glass transition temperature in the range 459-473 degrees C and 262-329 degrees C, respectively. |
| DOI | 10.1016/j.eurpolymj.2018.09.054 |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.741 |
Divison category:
Polymer Science & Engineering
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