Synthesis and characterization of hindered amine light stabilizers based on end functionalization of polypropylene
Title | Synthesis and characterization of hindered amine light stabilizers based on end functionalization of polypropylene |
Publication Type | Journal Article |
Year of Publication | 2007 |
Authors | K. Reddy, R, Kumar, B, Rana, S, Tevtia, AK, Singh, RP |
Journal | Journal of Applied Polymer Science |
Volume | 104 |
Issue | 3 |
Pagination | 1596-1602 |
Date Published | MAY |
Type of Article | Article |
ISSN | 0021-8995 |
Keywords | end functionalization, functionalization of polymers, polymeric HALS, polypropylene, vinylidine and photostabilization |
Abstract | A polymeric hindered amine light stabilizer (HALS), where HALS moiety was attached at the terminal end of the polypropylene chain via end-functionalized vinylidine PP through simple organic reactions, was synthesized. It comprises the synthesis of vinylidine-terminated polypropylene by using Cp2ZrCl2/MAO as catalyst system and epoxidation of vinylidene polypropylene. The final product was synthesized by carrying out the reaction between epoxy end functionalized polypropylene and 4-amino-2,2,6,6-tetrametyl piperidine. The final product was characterized by using H-1 NMR, C-13 NMR, and FT-IR spectra. Functionality was calculated by using vapor phase osmometry and H-1 NMR. The solubility and diffusion coefficient of the product were calculated and also its stabilization performance was checked. (c) 2007 Wiley Periodicals, Inc. |
DOI | 10.1002/app.25745 |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 1.866 |