Synthesis and characterization of ferrocenylchalcogenopropargyl complexes [Fe(eta(5)-(C5H4ECH2C)-C-I CH)(2)] (E-I = Se, S) and their reactions to form unusual ferrocenyl-containing metal clusters with eclipsed Cp rings and new five-membered (FeECH)-C-I =
| Title | Synthesis and characterization of ferrocenylchalcogenopropargyl complexes [Fe(eta(5)-(C5H4ECH2C)-C-I CH)(2)] (E-I = Se, S) and their reactions to form unusual ferrocenyl-containing metal clusters with eclipsed Cp rings and new five-membered (FeECH)-C-I = |
| Publication Type | Journal Article |
| Year of Publication | 2005 |
| Authors | Mathur, P, Singh, VK, Mobin, SM, Srinivasu, C, Trivedi, R, Bhunia, AK, Puranik, VG |
| Journal | Organometallics |
| Volume | 24 |
| Issue | 3 |
| Pagination | 367-372 |
| Date Published | JAN |
| Type of Article | Article |
| ISSN | 0276-7333 |
| Abstract | {The new bis(chalcogenopropargyl)ferrocene complexes [Fe(eta(5)-C(5)H(4)E(I)CH(2)CdropCH)(2)] (E-I = Se, 1; E-I = S, 2) have been prepared by treatment of the dilithiated [Fe(eta(5)-C5H4Li)(2)] with Se or S powder, followed by reaction with propargyl bromide. Reaction of 1 and 2 with [Fe2M(mu(3)-E)(2)(CO)(9)] (E = S, Se and M = Fe, Ru) forms new clusters which feature an unusual five-membered (FeECH)-C-I=CCH2 ring with a pi bond between the olefinic unit and the Fe atom, and the Cp rings adopt an eclipsed arrangement. The structures of 1 and [Fe(eta(5)-C5H4E(I)-CH(2)CdropCH) (eta(5)-C5H4{Fe2M(CO)(8)(mu-E)((ECHCCH2)-C-I)})] (M = Fe |
| DOI | 10.1021/om049226r |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 4.186 |
Divison category:
Center for Material Characterization (CMC)
Physical and Materials Chemistry