Synthesis and application of a chiral diborate

TitleSynthesis and application of a chiral diborate
Publication TypeJournal Article
Year of Publication2011
AuthorsLoewer, Y, Weiss, C, Biju, AT, Frohlich, R, Glorius, F
JournalJournal of Organic Chemistry
Volume76
Issue7
Pagination2324–2327
Date PublishedMAR
Abstract

A chiral diborate with different counterions is reported whose structure was unambiguously confirmed by X-ray analysis. This chiral dianion was used in the resolution of trans-1,2-diamines and also as a chiral shift reagent for NMR analysis of triphenylphosphonium salts.

DOI10.1021/jo102559s
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)4.45
Divison category: 
Organic Chemistry