Suzuki cross-coupling reactions catalyzed by palladium complex of an inexpensive phosphinite, 2-diphenylphosphinoxynaphthyl
| Title | Suzuki cross-coupling reactions catalyzed by palladium complex of an inexpensive phosphinite, 2-diphenylphosphinoxynaphthyl |
| Publication Type | Journal Article |
| Year of Publication | 2006 |
| Authors | Punji, B, Ganesamoorthy, C, Balakrishna, MS |
| Journal | Journal of Molecular Catalysis A-Chemical |
| Volume | 259 |
| Issue | 1-2 |
| Pagination | 78–83 |
| Date Published | NOV |
| Type of Article | Article |
| Abstract | A facile and less expensive monophosphinite ligand 2-(diphenylphosphinoxy)-naphthyl, C10H7OPPh2 (1) has been synthesized from the reaction of β-naphthol with chlorodiphenylphosphine. The mixture of Pd(OAc)2 and 1 catalyzes the Suzuki cross-coupling of a variety of aryl halides with aryl boronic acids at room temperature or at 60 °C, giving generally high yields even under low catalytic loads. The effect of solvent, base and catalyst loading on the coupling reaction of aryl halide with arylboronic acid is also described. |
| DOI | 10.1016/j.molcata.2006.05.067 |
| Funding Agency | Council of Scientific & Industrial Research (CSIR) - India |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 3.958 |
Divison category:
Organic Chemistry