Surface functionalization: an efficient alternative for promoting the catalytic activity of closed shell gold clusters

TitleSurface functionalization: an efficient alternative for promoting the catalytic activity of closed shell gold clusters
Publication TypeJournal Article
Year of Publication2020
AuthorsJoshi, K, Krishnamurty, S, Dar, MAhmad
JournalPhysical Chemistry Chemical Physics
Volume22
Issue40
Pagination23351-23359
Date PublishedOCT
Type of ArticleArticle
ISSN1463-9076
Abstract

{Surface functionalization through adsorption of ligands or non-metal atoms is considered to be an interesting and viable approach for tuning the physicochemical properties of gold clusters. Highly stable and magic numbered electronic configurations of thiolate protected gold clusters such as Au-25(SR)(18), Au-38(SR)(24)etc. with intriguing properties are the direct manifestation of the rich chemistry of the Au-S interface. The present investigation discerns the CO oxidation activity of structurally well characterized sulphur functionalized gold cluster anions AumS4-

DOI10.1039/d0cp01918f
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

3.430

Divison category: 
Physical and Materials Chemistry

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