Superior field emission properties of layered WS2-RGO nanocomposites

TitleSuperior field emission properties of layered WS2-RGO nanocomposites
Publication TypeJournal Article
Year of Publication2013
AuthorsRout, CSekhar, Joshi, PD, Kashid, RV, Joag, DS, More, MA, Simbeck, AJ, Washington, M, Nayak, SK, Late, DJ
JournalScientific Reports
Volume3
Pagination3282
Date PublishedNOV
ISSN2045-2322
Abstract

We report here the field emission studies of a layered WS2-RGO composite at the base pressure of similar to 1 x 10(-8) mbar. The turn on field required to draw a field emission current density of 1 mu A/cm(2) is found to be 3.5, 2.3 and 2 V/mu m for WS2, RGO and the WS2-RGO composite respectively. The enhanced field emission behavior observed for the WS2-RGO nanocomposite is attributed to a high field enhancement factor of 2978, which is associated with the surface protrusions of the single-to-few layer thick sheets of the nanocomposite. The highest current density of similar to 800 mu A/cm(2) is drawn at an applied field of 4.1 V/mu m from a few layers of the WS2-RGO nanocomposite. Furthermore, first-principles density functional calculations suggest that the enhanced field emission may also be due to an overalp of the electronic structures of WS2 and RGO, where graphene-like states are dumped in the region of the WS2 fundamental gap.

DOI10.1038/srep03282
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)5.078
Divison category: 
Physical and Materials Chemistry