Sulfonamide- and hydrazine-based palladium catalysts: stable and efficient catalysts for C-C coupling reactions in aqueous medium

TitleSulfonamide- and hydrazine-based palladium catalysts: stable and efficient catalysts for C-C coupling reactions in aqueous medium
Publication TypeJournal Article
Year of Publication2007
AuthorsKumar, NSCRame, I. Raj, VPaul, Sudalai, A
JournalJournal of Molecular Catalysis A-Chemical
Volume269
Issue1-2
Pagination218-224
Date PublishedMAY
Type of ArticleArticle
ISSN1381-1169
Keywordsarylation reaction, Heck reaction, palladium catalyst, Sonogashira reaction, Suzuki coupling reaction
Abstract

Syntheses of a novel family of sulfonamide-based palladium complexes and phenylhydrazine-based palladacycles are described. These catalysts are thermally stable, and not sensitive to air and moisture and some are completely soluble in water. These catalysts have shown excellent activity (good yields and high turnover numbers) and product selectivity in several arylation reactions including Suzuki, Heck, and Sonogashira reactions carried out totally under aqueous conditions. (c) 2006 Elsevier B.V. All rights reserved.

DOI10.1016/j.molcata.2006.12.023
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)3.958
Divison category: 
Chemical Engineering & Process Development