State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide via cyclic carbonates and oxazolidinones
| Title | State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide via cyclic carbonates and oxazolidinones |
| Publication Type | Journal Article |
| Year of Publication | 2016 |
| Authors | Saptal, V, Shinde, DBalaji, Banerjee, R, Bhanage, BM |
| Journal | Catalysis Science & Technology |
| Volume | 6 |
| Issue | 15 |
| Pagination | 6152-6158 |
| Date Published | MAY |
| Abstract | A highly porous, crystalline catechol porphyrin COF was synthesized and applied as an organocatalyst for the chemical fixation of carbon dioxide to synthesize value-added chemicals such as cyclic carbonates and oxazolidinones under solvent-free and transition-metal-free conditions. The high surface area and the functionalities of the COF catalyst act synergistically to activate the starting material. The 2,3-DhaTph shows excellent activity towards cyclic carbonates at the atmospheric pressure of carbon dioxide. Additionally, this catalytic system is recyclable in nature and provides a higher turnover number than previously reported organocatalysts. |
| DOI | 10.1039/c6cy00362a |
| Type of Journal (Indian or Foreign) | Foreign |
| Impact Factor (IF) | 5.287 |
Divison category:
Physical and Materials Chemistry