Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning
Title | Stabilization of graphene quantum dots (GQDs) by encapsulation inside zeolitic imidazolate framework nanocrystals for photoluminescence tuning |
Publication Type | Journal Article |
Year of Publication | 2013 |
Authors | Biswal, BP, Shinde, DB, Pillai, VK, Banerjee, R |
Journal | Nanoscale |
Volume | 5 |
Issue | 21 |
Pagination | 10556-10561 |
Date Published | SEP |
ISSN | 2040-3364 |
Abstract | Luminescent graphene quantum dots (GQDs) are encapsulated and stabilized in Zeolitic Imidazolate Framework (ZIF-8) nanocrystals. The GQDs are well confined due to the adsorption on the growing face of the ZIF-8 nanocrystals and have a profound effect on the shape of the nanocrystals from rhombic dodecahedron to spherical. Stabilizing GQDs inside the ZIF-8 nanocrystals results in tailoring of the photoluminescence emission (ca. 32 nm, bathochromic shift) of the GQD@ZIF-8 nanocrystal composite even after 3 months of aging under normal laboratory conditions. Also the water adsorption (at STP) capacity increased for the GQD@ ZIF-8 composite as compared to the pristine ZIF-8. |
DOI | 10.1039/c3nr03511e |
Type of Journal (Indian or Foreign) | Foreign |
Impact Factor (IF) | 6.739 |
Divison category:
Physical and Materials Chemistry