In situ encapsulation of pt nanoarchitectures of varying morphologies in mesoporous compounds

TitleIn situ encapsulation of pt nanoarchitectures of varying morphologies in mesoporous compounds
Publication TypeJournal Article
Year of Publication2010
AuthorsPrashar, AK, Hodgkins, RP, Chandran, JN, Rajamohanan, PR, R. Devi, N
JournalChemistry of Materials
Volume22
Issue5
Pagination1633-1639
Date PublishedMAR
ISSN0897-4756
Abstract

Nanoparticle morphology could be engineered and fine-tuned based on a novel in situ template method Different shapes of platinum nanoparticles were obtained from very low concentrations of precursors and could be isolated exclusively inside the mesochannels of SBA-15 This was achieved by dispersing a platinum precursor in surfactant modified polymer to different extents and using these composite materials as templates for the formation of mesoporous silica [PtCl(6)](2-) interacts with the cationic headgroup of the surfactant and facilitates the isolation of precursors within the composite template leading to the formation of nanoparticles molded by the walls of the mesochannels when calcined When this [PtCl(6)](2-)-surfactant-polymer micelle composite is aged for different duration, Pt nanoparticles of various morphologies like spheroids, nano rugby balls, and nanorods are obtained

DOI10.1021/cm9036499
Type of Journal (Indian or Foreign)Foreign
Impact Factor (IF)6.397
Divison category: 
Catalysis and Inorganic Chemistry
Central NMR Facility