Short synthesis of (+)-harzialactone A and (R)-(+)-4-hexanolide via proline-catalyzed sequential alpha-aminooxylation and horner-wadsworth-emmons olefination of aldehydes

TitleShort synthesis of (+)-harzialactone A and (R)-(+)-4-hexanolide via proline-catalyzed sequential alpha-aminooxylation and horner-wadsworth-emmons olefination of aldehydes
Publication TypeJournal Article
Year of Publication2007
AuthorsKotkar, SP, Suryavanshi, GS, Sudalai, A
JournalTetrahedron-Asymmetry
Volume18
Issue15
Pagination1795-1798
Date PublishedAUG
Type of ArticleArticle
ISSN0957-4166
Keywordscore-shell nanoparticles, Gold, HRTEM, interfacial seeded growth, Silver, XPS
Abstract

{In melts, ring polymers assume more compact conformations compared to linear chains with the same degree of polymerization N-r, i.e. R-r similar to N-r(nu) with nu approximate to 0.4, where R-r is the radius of gyration. Upon gradually substituting some of the ring polymers with linear chains, the ring molecules swell. In the limit of infinite dilution, their size scales as R-r similar to N-r(0.5). We present a scaling argument based on the blob model to capture this transition. Ring-linear blends are modeled as a semidilute solution of ring polymers in a theta-solvent consisting of linear chains. The model predicts that the size of the ring polymer remains unchanged up to the overlap concentration c(r)(*

DOI10.1016/j.tetasy.2007.07.031
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

2.108

Divison category: 
Chemical Engineering & Process Development